Record Information
Version1.0
Creation date2010-04-08 22:05:57 UTC
Update date2019-11-26 02:59:35 UTC
Primary IDFDB003789
Secondary Accession NumbersNot Available
Chemical Information
FooDB NameTitanium
DescriptionA metallic element, titanium is recognized for its high strength-to-weight ratio. It is a strong metal with low density that is quite ductile (especially in an oxygen-free environment), lustrous, and metallic-white in color. The relatively high melting point (over 1,649 °C or 3,000 °F) makes it useful as a refractory metal.; A more recently developed method, the FFC Cambridge process, may eventually replace the Kroll process. This method uses titanium dioxide powder (which is a refined form of rutile) as feedstock to make the end product which is either a powder or sponge. If mixed oxide powders are used, the product is an alloy manufactured at a much lower cost than the conventional multi-step melting process. The FFC Cambridge process may render titanium a less rare and expensive material for the aerospace industry and the luxury goods market, and could be seen in many products currently manufactured using aluminium and specialist grades of steel.; Due to their high tensile strength to density ratio, high corrosion resistance, and ability to withstand moderately high temperatures without creeping, titanium alloys are used in aircraft, armor plating, naval ships, spacecraft, and missiles. For these applications titanium alloyed with aluminium, vanadium, and other elements is used for a variety of components including critical structural parts, fire walls, landing gear, exhaust ducts (helicopters), and hydraulic systems. In fact, about two thirds of all titanium metal produced is used in aircraft engines and frames. The SR-71 "Blackbird" was one of the first aircraft to make extensive use of titanium within its structure, paving the way for its use in modern military and commercial aircraft. An estimated 59 metric tons (130,000 pounds) are used in the Boeing 777, 45 in the Boeing 747, 18 in the Boeing 737, 32 in the Airbus A340, 18 in the Airbus A330, and 12 in the Airbus A320. The Airbus A380 may use 146 metric tons, including about 26 tons in the engines. In engine applications, titanium is used for rotors, compressor blades, hydraulic system components, and nacelles. The titanium 6AL-4V alloy accounts for almost 50% of all alloys used in aircraft applications.; The metal is a dimorphic allotrope with the hexagonal alpha form changing into the body-centered cubic (lattice) ? form at 882 °C (1,620 °F). The specific heat of the alpha form increases dramatically as it is heated to this transition temperature but then falls and remains fairly constant for the ? form regardless of temperature. Similar to zirconium and hafnium, an additional omega phase exists, which is thermodynamically stable at high pressures, but is metastable at ambient pressures. This phase is usually hexagonal (ideal) or trigonal (distorted) and can be viewed as being due to a soft longitudinal acoustic phonon of the ? phase causing collapse of (111) planes of atoms.; Titanium (pronounced /ta??te?ni?m/, tye-TAY-nee-?m) is a chemical element with the symbol Ti and atomic number 22. Sometimes called the ?space age metal?, it has a low density and is a strong, lustrous, corrosion-resistant (including sea water, aqua regia and chlorine) transition metal with a silver color.; Titanium burns in air when heated to 1,200 °C (2,190 °F) and in pure oxygen when heated to 610 °C (1,130 °F) or higher, forming titanium dioxide. As a result, the metal cannot be melted in open air as it burns before the melting point is reached, so melting is only possible in an inert atmosphere or in a vacuum. It is also one of the few elements that burns in pure nitrogen gas (it burns at 800 °C or 1,472 °F and forms titanium nitride, which causes embrittlement). Titanium is resistant to dilute sulfuric acid and hydrochloric acid, along with chlorine gas, chloride solutions, and most organic acids. It is paramagnetic (weakly attracted to magnets) and has fairly low electrical and thermal conductivity.; Titanium is a light, strong, lustrous, corrosion-resistant (including resistance to sea water and chlorine) transition metal with a white-silvery-metallic color; Titanium tetrachloride (titanium(IV) chloride, TiCl4, sometimes called "Tickle") is a colorless liquid which is used as an intermediate in the manufacture of titanium dioxide for paint. It is widely used in organic chemistry as a Lewis acid, for example in the Mukaiyama aldol condensation. Titanium also forms a lower chloride, titanium(III) chloride (TiCl3), which is used as a reducing agent.; Titanocene dichloride is an important catalyst for carbon-carbon bond formation. Titanium isopropoxide is used for Sharpless epoxidation. Other compounds include titanium bromide (used in metallurgy, superalloys, and high-temperature electrical wiring and coatings) and titanium carbide (found in high-temperature cutting tools and coatings).; analysis of particles found in lung tissues obtained by open lung biopsies demonstrated the presence of titanium. ; Salts of titanium are often considered to be relatively harmless but its chlorine compounds, such as TiCl2, TiCl3 and TiCl4, have unusual hazards. The dichloride takes the form of pyrophoric black crystals, and the tetrachloride is a volatile fuming liquid. All of titanium's chlorides are corrosive. (PMID: 7606971, 14756054, 16958916); in the periodic table it has the symbol Ti and atomic number 22.; Titanium and its alloys are used for medical purpose like osteosynthesis, arthroplasty, pacemaker encasing, orthodontical wires, or in daily-use articles like spectacle frames. At a composition of 50% nickel and 50% titanium, the material nitinol can be folded but returns at given temperatures to its original form without damage. This shape memory effect is used for spectacle frames, flexible tubes, intravascular stents, or orthodontic wires. When exposing the latter to an acidic environment, a substantial nickel and titanium release can be observed. However, even 'pure' titanium materials used for implant alloys may contain nickel as result of the production process. Standard titanium alloys (TiAl6Nb7, TiAl6V4) and pure titanium discs supplied by five different titanium manufactures were shown to contain up to 0.034 wt % nickel, with iodide-titanium having the lowest percentage (0.002 wt %). Here, the nickel atoms are reported to be in solid solution in the titanium lattice. Suspected delayed-type hypersensitivity reactions to titanium were first reported as pacemaker dermatitis, but their existence is still put in question due to not always complete allergological work up and insufficient patch test preparations. In 1984, Peters et al. described a patient who had repeatedly cardiac pacemakers implanted and removed because pruritus, redness, and swelling of the skin overlying the pacemaker had developed within several weeks after insertion. These reactions were interpreted as contact sensitivity to the pure titanium encasing of the pacemaker, as there was a ++ patch test reaction to a thin square of metallic titanium applied with artificial sweat. ; Physiologically, it exists as an ion in the body. Humans exposed to titanium can develop pulmonary alveolar proteinosis (PAP, a disease of obscure cause that is characterized by the accumulation of a granular material that contains abundant lipid within the alveoli of lung.) with severe respiratory failure.
CAS Number7440-32-6
Structure
Thumb
Synonyms
SynonymSource
22TiChEBI
TiChEBI
TitanChEBI
TitaneChEBI
TitanioChEBI
Adaptive Fps 10biospider
Alpaste RTA 030biospider
Aquasmooth makeupbiospider
ATI 24HMDB
Aveda Moisture Plus Tint Spf 15biospider
Avon Beyond Color Perfecting Foundation Spf 12biospider
Beauticontrol color freeze liquid makeupbiospider
C.p. titaniumbiospider
Clinique Almost Makeup Spf 15biospider
Clinique City Base Compact Foundation Spf 15biospider
Clinique City Cover Compact Concealer Spf 15biospider
Clinique Continuous Coverage Spf 15biospider
Clinique Dewy Smooth Anti-Aging Makeup Spf 15biospider
Contimet 30biospider
Cover girl fresh look makeupbiospider
CP titaniumbiospider
Creme de Soins Hydratante Teintee Honey Spf6biospider
DAT 1biospider
DAT 5Ebiospider
Dentcraft titan ingotbiospider
Dermalogica Ultra Sensitive Face Block Spf 25biospider
Double Perfection Compact Spf 10biospider
Double Wear Stay -in- Place Makeup Spf 10biospider
Ebt (metal)biospider
Estee Lauder Double Wear Stay-in-Place Concealer Spf 10biospider
Estee Lauder Equalizer Smart Makeup for Combination Skin Spf 10biospider
Estee Lauder Re-Nutriv Intensive Lifting Makeup Spf 15biospider
G.M. Collin Ecran Solaire Total Spf 30biospider
G.M. Collin Protection Solaire Total Spf 15biospider
G.M. Collin Vapo Protection Spf 14biospider
Ideal Balance Spf 14biospider
Jistp28biospider
Luxiva Face the Day Creme-to-Powder Makeup Spf 25biospider
Luxiva Lasting Foundation Spf 12biospider
Men's Titanium 15 - Crm 6%biospider
Men's Titanium 4 - Crm 2%biospider
Neutrogena Spf 30 Sensitive Skinbiospider
Oi-Lin Natural Emulsion Spf 30biospider
Oremetbiospider
Photogenic Concealer Spf 15biospider
PTKh 2biospider
Revlon new complexion one step make-upbiospider
Roc Minesol Spf 30biospider
Smelloff-cutter titaniumbiospider
Stila Illuminating Powder Foundation Spf 12biospider
Sun Mineral Sunscreen 18 Spf for Sensitive Skin Alba Botanicabiospider
Super City Block Spf 25biospider
TIbiospider
Titan vt 1-1biospider
Titanatebiospider
Titanium (DRY powder)biospider
Titanium 50Abiospider
Titanium A-40biospider
Titanium alloybiospider
Titanium elementbiospider
Titanium fulleride (TiC20)biospider
Titanium hydridebiospider
Titanium metal powder, DRYbiospider
Titanium metallicumbiospider
Titanium Metallicum Liquid (S#68)-3,6,9x..Cmbiospider
Titanium VT1biospider
Titanium-125biospider
TITANIUM, 99.8%biospider
Titanium, ion (Ti1+)biospider
Titanium(II) hydridebiospider
Tiunitebiospider
Vapo Ecran Solaire Fps 15biospider
VT 1 Lbiospider
VT-1Dbiospider
VTl-0biospider
Predicted Properties
PropertyValueSource
logP0ChemAxon
Physiological Charge0ChemAxon
Hydrogen Acceptor Count0ChemAxon
Hydrogen Donor Count0ChemAxon
Polar Surface Area0 ŲChemAxon
Rotatable Bond Count0ChemAxon
Refractivity0 m³·mol⁻¹ChemAxon
Polarizability1.78 ųChemAxon
Number of Rings0ChemAxon
BioavailabilityYesChemAxon
Rule of FiveYesChemAxon
Ghose FilterNoChemAxon
Veber's RuleYesChemAxon
MDDR-like RuleNoChemAxon
Chemical FormulaTi
IUPAC nametitanium
InChI IdentifierInChI=1S/Ti
InChI KeyRTAQQCXQSZGOHL-UHFFFAOYSA-N
Isomeric SMILES[Ti]
Average Molecular Weight47.867
Monoisotopic Molecular Weight47.947947053
Classification
Description Belongs to the class of inorganic compounds known as homogeneous transition metal compounds. These are inorganic compounds containing only metal atoms,with the largest atom being a transition metal atom.
KingdomInorganic compounds
Super ClassHomogeneous metal compounds
ClassHomogeneous transition metal compounds
Sub ClassNot Available
Direct ParentHomogeneous transition metal compounds
Alternative ParentsNot Available
Substituents
  • Homogeneous transition metal
Molecular FrameworkNot Available
External Descriptors
Ontology
OntologyNo ontology term
Physico-Chemical Properties - Experimental
Physico-Chemical Properties - Experimental
PropertyValueReference
Physical stateSolid
Physical DescriptionNot Available
Mass CompositionNot Available
Melting Point1668 oC
Boiling PointNot Available
Experimental Water SolubilityNot Available
Experimental logPNot Available
Experimental pKaNot Available
Isoelectric pointNot Available
ChargeNot Available
Optical RotationNot Available
Spectroscopic UV DataNot Available
DensityNot Available
Refractive IndexNot Available
Spectra
Spectra
EI-MS/GC-MSNot Available
MS/MS
TypeDescriptionSplash KeyView
Predicted MS/MSPredicted LC-MS/MS Spectrum - 10V, Positivesplash10-0002-9000000000-47e5da0937d003fd9f3fSpectrum
Predicted MS/MSPredicted LC-MS/MS Spectrum - 20V, Positivesplash10-0002-9000000000-47e5da0937d003fd9f3fSpectrum
Predicted MS/MSPredicted LC-MS/MS Spectrum - 40V, Positivesplash10-0002-9000000000-47e5da0937d003fd9f3fSpectrum
Predicted MS/MSPredicted LC-MS/MS Spectrum - 10V, Negativesplash10-0002-9000000000-7ac118264f854b5c0359Spectrum
Predicted MS/MSPredicted LC-MS/MS Spectrum - 20V, Negativesplash10-0002-9000000000-7ac118264f854b5c0359Spectrum
Predicted MS/MSPredicted LC-MS/MS Spectrum - 40V, Negativesplash10-0002-9000000000-7ac118264f854b5c0359Spectrum
NMRNot Available
ChemSpider ID102881
ChEMBL IDNot Available
KEGG Compound IDNot Available
Pubchem Compound ID114942
Pubchem Substance IDNot Available
ChEBI ID33341
Phenol-Explorer IDNot Available
DrugBank IDNot Available
HMDB IDHMDB01966
CRC / DFC (Dictionary of Food Compounds) IDNot Available
EAFUS IDNot Available
Dr. Duke IDTITANIUM
BIGG IDNot Available
KNApSAcK IDNot Available
HET IDNot Available
Food Biomarker OntologyNot Available
VMH IDNot Available
Flavornet IDNot Available
GoodScent IDNot Available
SuperScent IDNot Available
Wikipedia IDTitanium
Phenol-Explorer Metabolite IDNot Available
Duplicate IDSNot Available
Old DFC IDSNot Available
Associated Foods
FoodContent Range AverageReference
FoodReference
Biological Effects and Interactions
Health Effects / BioactivitiesNot Available
EnzymesNot Available
PathwaysNot Available
MetabolismNot Available
BiosynthesisNot Available
Organoleptic Properties
FlavoursNot Available
Files
MSDSshow
References
Synthesis ReferenceNot Available
General ReferenceNot Available
Content Reference— Duke, James. 'Dr. Duke's Phytochemical and Ethnobotanical Databases. United States Department of Agriculture.' Agricultural Research Service, Accessed April 27 (2004).