1.0 2010-04-08 22:06:32 UTC 2025-11-18 22:58:16 UTC FDB005117 Glucosan Glucosan is a monosaccharide anhydride compound present in biomass combustion smoke, and is a tracer for biomass burning sources in atmospheric aerosol particles. A product of cellulose combustion; when cellulose is heated to over 300 degree centigrade, it undergoes various pyrolytic processes, yielding a highly combustible tar, a major constituent of which is glucosan, a dehydrated glucose containing a ketal functional group.; Glucosan is a saccharide constituent of human urine, detected with one-dimensional thin-layer chromatography, and further studied by gas chromatography-mass spectrometry. It was identified in approximately 20% of all urine samples investigated. Excretory levels varied widely from zero up to 5.3 mmol/l. (PMID: 3757263, 16448658, 16317539). Glucosan is found in sweet orange. β-D-Glucopyranose, 1,6-anhydro- 1,6-Anhydro-β-D-glucopyranose 1,6-Anhydro-β-D-glucopyranose (levoglucosan) 1,6-Anhydro-b-D-glucopyranose 1,6-Anhydro-b-D-glucose 1,6-Anhydro-b-glucopyranose 1,6-Anhydro-beta-D-glucopyranose 1,6-Anhydro-beta-D-glucose 1,6-Anhydro-beta-delta-glucopyranose 1,6-Anhydro-beta-delta-glucose 1,6-Anhydro-beta-glucopyranose 1,6-Anhydro-D-glucose 1,6-Anhydro-delta-glucose 1,6-Anhydro-β-D-glucose 1,6-Anhydro-β-glucopyranose 1,6-Anhydroglucose 6,8-Dioxabicyclo[3.2.1]octane b-D-glucopyranose deriv. 6,8-Dioxabicyclo[3.2.1]octane b-delta-glucopyranose deriv. Anhydro-d-mannosan Anhydro-delta-mannosan L-Glucosan Leucoglucosan Levoglucosan C6H10O5 162.1406 162.05282343 6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol levoglucosan 498-07-7 OC1C2COC(O2)C(O)C1O InChI=1S/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2 TWNIBLMWSKIRAT-UHFFFAOYSA-N belongs to the class of organic compounds known as oxepanes. Oxepanes are compounds containing an oxepane ring, which is a seven-member saturated aliphatic heterocycle with one oxygen and six carbon atoms. Oxepanes Organic compounds Organoheterocyclic compounds Oxepanes Aliphatic heteropolycyclic compounds 1,3-dioxolanes Acetals Hydrocarbon derivatives Monosaccharides Oxacyclic compounds Oxanes Polyols Secondary alcohols Acetal Alcohol Aliphatic heteropolycyclic compound Hydrocarbon derivative Meta-dioxolane Monosaccharide Organic oxygen compound Organooxygen compound Oxacycle Oxane Oxepane Polyol Secondary alcohol a hexose Solid logp -2.18 ALOGPS logs 0.99 ALOGPS solubility 1.60e+03 g/l ALOGPS melting_point 183 oC logp -1.8 ChemAxon pka_strongest_acidic 12.21 ChemAxon pka_strongest_basic -3.6 ChemAxon iupac 6,8-dioxabicyclo[3.2.1]octane-2,3,4-triol ChemAxon average_mass 162.1406 ChemAxon mono_mass 162.05282343 ChemAxon smiles OC1C2COC(O2)C(O)C1O ChemAxon formula C6H10O5 ChemAxon inchi InChI=1S/C6H10O5/c7-3-2-1-10-6(11-2)5(9)4(3)8/h2-9H,1H2 ChemAxon inchikey TWNIBLMWSKIRAT-UHFFFAOYSA-N ChemAxon polar_surface_area 79.15 ChemAxon refractivity 32.41 ChemAxon polarizability 14 ChemAxon rotatable_bond_count 0 ChemAxon acceptor_count 5 ChemAxon donor_count 3 ChemAxon physiological_charge 0 ChemAxon formal_charge 0 ChemAxon Specdb::NmrOneD 4673 Specdb::NmrOneD 4698 HMDB00640 30997 #<Reference:0x00007f093c0eb310> #<Reference:0x00007f093c0eaf78> #<Reference:0x00007f093c0eaca8> #<Reference:0x00007f093c0eaaf0> #<Reference:0x00007f093c0ea8e8> Beer Type 2 specific 0.094 0.108 0.08 mg/100 g Sweet orange Type 1 specific Citrus sinensis 2711