<?xml version="1.0" encoding="UTF-8"?>
<compound>
  <version>1.0</version>
  <creation_date>2010-04-08 22:10:35 UTC</creation_date>
  <update_date>2025-11-18 23:42:16 UTC</update_date>
  <accession>FDB013208</accession>
  <name>Iron(III) chloride</name>
  <description>Nutrient supplement

Iron(III) chloride is a mild oxidising agent, for example capable of oxidising copper(I) chloride to copper(II) chloride. Reducing agents such as hydrazine convert iron(III) chloride to complexes of iron(II).; Iron(III) chloride is a moderately strong Lewis acid, forming adducts with Lewis bases such as triphenylphosphine oxide, e.g. FeCl3(OPPh3)2 where Ph = phenyl.; Iron(III) chloride, also called ferric chloride, is an industrial scale commodity chemical compound, with the formula FeCl3. The colour of iron(III) chloride crystals depends on the viewing angle: by reflected light the crystals appear dark green, but by transmitted light they appear purple-red. Anhydrous iron(III) chloride is deliquescent, forming hydrated hydrogen chloride mists in moist air. It is rarely observed in its natural form, mineral molysite, known mainly from some fumaroles.; The ferric chloride test is a traditional colorimetric test for phenols, which uses a 1% iron(III) chloride solution that has been neutralised with sodium hydroxide until a slight precipitate of FeO(OH) is formed. The mixture is filtered before use. The organic substance is dissolved in water, methanol or ethanol, then the neutralised iron(III) chloride solution is added?a transient or permanent coloration (usually purple, green or blue) indicates the presence of a phenol or enol.; When dissolved in water, iron(III) chloride undergoes hydrolysis and gives off heat in an exothermic reaction. The resulting brown, acidic, and corrosive solution is used as a coagulant in sewage treatment and drinking water production, and as an etchant for copper-based metals in printed circuit boards. Anhydrous iron(III) chloride is a fairly strong Lewis acid, and it is used as a catalyst in organic synthesis.</description>
  <synonyms>
    <synonym>[FeCl3]</synonym>
    <synonym>Chlorure ferrique</synonym>
    <synonym>Chlorure perrique</synonym>
    <synonym>FeCl3</synonym>
    <synonym>Ferric chloride</synonym>
    <synonym>Ferric chloride anhydrous</synonym>
    <synonym>Ferric Chloride Fe 59</synonym>
    <synonym>Ferric chloride, anhydrous</synonym>
    <synonym>Ferric chloride, anhydrous [UN1773] [Corrosive]</synonym>
    <synonym>Ferric chloride, solid</synonym>
    <synonym>Ferric chloride, solid (dot)</synonym>
    <synonym>Ferric chloride, solid, anhydrous</synonym>
    <synonym>Ferric chloride, solid, anhydrous (dot)</synonym>
    <synonym>Ferric trichloride</synonym>
    <synonym>Flores martis</synonym>
    <synonym>Iron (III) chloride</synonym>
    <synonym>Iron atomic spectroscopy standard concentrate 1.00 g Fe</synonym>
    <synonym>Iron chloride</synonym>
    <synonym>Iron chloride (Fe2Cl3)</synonym>
    <synonym>Iron chloride (FeCl3)</synonym>
    <synonym>Iron chloride, solid</synonym>
    <synonym>Iron chloride, solid (dot)</synonym>
    <synonym>Iron perchloride</synonym>
    <synonym>Iron sesquichloride</synonym>
    <synonym>Iron sesquichloride (dot)</synonym>
    <synonym>Iron standard concentrate 10.00 g Fe</synonym>
    <synonym>Iron trichloride</synonym>
    <synonym>iron(3+) chloride</synonym>
    <synonym>iron(3+) trichloride</synonym>
    <synonym>Natural molysite</synonym>
    <synonym>Perchlorure de fer</synonym>
  </synonyms>
  <chemical_formula>Cl3Fe</chemical_formula>
  <average_molecular_weight>162.204</average_molecular_weight>
  <monisotopic_moleculate_weight>160.841500254</monisotopic_moleculate_weight>
  <iupac_name>iron(3+) ion trichloride</iupac_name>
  <traditional_iupac>iron(3+) ion trichloride</traditional_iupac>
  <cas_registry_number>7705-08-0</cas_registry_number>
  <smiles>[Cl-].[Cl-].[Cl-].[Fe+3]</smiles>
  <inchi>InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3</inchi>
  <inchikey>RBTARNINKXHZNM-UHFFFAOYSA-K</inchikey>
  <taxonomy>
    <description> belongs to the class of inorganic compounds known as transition metal chlorides. These are inorganic compounds in which the largest halogen atom is Chlorine, and the heaviest metal atom is a transition metal.</description>
    <direct_parent>Transition metal chlorides</direct_parent>
    <kingdom>Inorganic compounds</kingdom>
    <super_class>Mixed metal/non-metal compounds</super_class>
    <class>Transition metal salts</class>
    <sub_class>Transition metal chlorides</sub_class>
    <molecular_framework/>
    <alternative_parents>
      <alternative_parent>Inorganic chloride salts</alternative_parent>
    </alternative_parents>
    <substituents>
      <substituent>Inorganic chloride salt</substituent>
      <substituent>Inorganic salt</substituent>
      <substituent>Transition metal chloride</substituent>
    </substituents>
    <external_descriptors>
      <external_descriptor>iron coordination entity</external_descriptor>
    </external_descriptors>
  </taxonomy>
  <state/>
  <predicted_properties>
  </predicted_properties>
  <experimental_properties>
    <property>
      <kind>melting_point</kind>
      <value>Mp 303° dec.</value>
    </property>
  </experimental_properties>
  <property>
    <kind>logp</kind>
    <value>-0.77</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>pka_strongest_acidic</kind>
    <value>-7</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>iupac</kind>
    <value>iron(3+) ion trichloride</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>average_mass</kind>
    <value>162.204</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>mono_mass</kind>
    <value>160.841500254</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>smiles</kind>
    <value>[Cl-].[Cl-].[Cl-].[Fe+3]</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>formula</kind>
    <value>Cl3Fe</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>inchi</kind>
    <value>InChI=1S/3ClH.Fe/h3*1H;/q;;;+3/p-3</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>inchikey</kind>
    <value>RBTARNINKXHZNM-UHFFFAOYSA-K</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>polar_surface_area</kind>
    <value>0</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>refractivity</kind>
    <value>0</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>polarizability</kind>
    <value>1.78</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>rotatable_bond_count</kind>
    <value>0</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>acceptor_count</kind>
    <value>0</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>donor_count</kind>
    <value>0</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>physiological_charge</kind>
    <value>-1</value>
    <source>ChemAxon</source>
  </property>
  <property>
    <kind>formal_charge</kind>
    <value>0</value>
    <source>ChemAxon</source>
  </property>
  <pathways>
  </pathways>
  <spectra>
    <spectrum>
      <type>Specdb::MsMs</type>
      <spectrum_id>95250</spectrum_id>
    </spectrum>
    <spectrum>
      <type>Specdb::MsMs</type>
      <spectrum_id>95251</spectrum_id>
    </spectrum>
    <spectrum>
      <type>Specdb::MsMs</type>
      <spectrum_id>95252</spectrum_id>
    </spectrum>
    <spectrum>
      <type>Specdb::MsMs</type>
      <spectrum_id>159453</spectrum_id>
    </spectrum>
    <spectrum>
      <type>Specdb::MsMs</type>
      <spectrum_id>159454</spectrum_id>
    </spectrum>
    <spectrum>
      <type>Specdb::MsMs</type>
      <spectrum_id>159455</spectrum_id>
    </spectrum>
  </spectra>
  <hmdb_id/>
  <pubchem_compound_id/>
  <chemspider_id/>
  <kegg_id/>
  <chebi_id>30808</chebi_id>
  <biocyc_id/>
  <het_id/>
  <wikipidia/>
  <vmh_id/>
  <fbonto_id/>
  <foodb_id/>
  <general_references>
  </general_references>
  <foods>
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  <flavors>
  </flavors>
  <enzymes>
  </enzymes>
  <health_effects>
  </health_effects>
</compound>
