Record Information
Version1.0
Creation date2010-04-08 22:06:07 UTC
Update date2019-11-26 02:59:52 UTC
Primary IDFDB004188
Secondary Accession NumbersNot Available
Chemical Information
FooDB NameSilver
DescriptionAmong metals, pure silver has the highest thermal conductivity (the non-metal diamond and superfluid helium II are higher) and one of the highest optical reflectivity. (Aluminium slightly outdoes silver in parts of the visible spectrum, and silver is a poor reflector of ultraviolet light). Silver also has the lowest contact resistance of any metal. Silver halides are photosensitive and are remarkable for their ability to record a latent image that can later be developed chemically. Silver is stable in pure air and water, but tarnishes when it is exposed to air or water containing ozone or hydrogen sulfide to form a black layer of silver sulfide which can be cleaned off with dilute hydrochloric acid. The most common oxidation state of silver is +1 (for example, silver nitrate: AgNO3); in addition, +2 compounds (for example, silver(II) fluoride: AgF2) and +3 compounds (for example, potassium tetrafluoroargentate: K[AgF4]) are known.; Hippocrates, the "father of medicine", wrote that silver had beneficial healing and anti-disease properties, and the Phoenicians used to store water, wine, and vinegar in silver bottles to prevent spoiling. In the early 1900s people would put silver dollars in milk bottles to prolong the milk's freshness. Its germicidal effects increased its value in utensils and as jewellery. The exact process of silver's germicidal effect is still not well understood, although theories exist. One of these is the oligodynamic effect, which explains the effect on microorganisms but would not explain antiviral effects.; Jewellery and silverware are traditionally made from sterling silver (standard silver), an alloy of 92.5% silver with 7.5% copper. In the United States, only an alloy consisting of at least 92.5% fine silver can be marketed as "silver". Sterling silver is harder than pure silver, and has a lower melting point (893 °C) than either pure silver or pure copper. Britannia silver is an alternative hallmark-quality standard containing 95.8% silver, often used to make silver tableware and wrought plate. With the addition of germanium, the patented modified alloy Argentium Sterling Silver is formed, with improved properties including resistance to firescale.; Silver bromide is a yellow, low hardness salt.; Silver is a chemical element with the chemical symbol Ag (Latin: argentum) and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal. The metal occurs naturally in its pure, free form (native silver), as an alloy with gold (electrum) and other metals, and in minerals such as argentite and chlorargyrite. Most silver is produced as a by-product of copper, gold, lead, and zinc refining.; Silver is a constituent of almost all colored carat gold alloys and carat gold solders, giving the alloys paler colour and greater hardness. White 9 carat gold contains 62.5% silver and 37.5% gold, while 22 carat gold contains up to 8.4% silver or 8.4% copper.; Silver is a very ductile and malleable (slightly harder than gold) monovalent coinage metal with a brilliant white metallic luster that can take a high degree of polish. It has the highest electrical conductivity of all metals, even higher than copper, but its greater cost and tarnishability have prevented it from being widely used in place of copper for electrical purposes, though 13,540 tons were used in the electromagnets used for enriching uranium during World War II (mainly because of the wartime shortage of copper). Another notable exception is in high-end audio cables.; Silver is commonly used in catheters. Silver alloy catheters are more effective than standard catheters for reducing bacteriuria in adults in hospital having short term catheterisation.This meta-analysis clarifies discrepant results among trials of silver-coated urinary catheters by revealing that silver alloy catheters are significantly more effective in preventing urinary tract infections than are silver oxide catheters. Though silver alloy urinary catheters cost about $6 more than standard urinary catheters, they may be worth the extra cost since catheter-related infection is a common cause of nosocomial infection and bacteremia.; Silver is widely distributed in the earth's crust and is found in soil, fresh and sea water, and the air. It is readily absorbed into the human body with food and drink and through inhalation, but the low levels of silver commonly present in the bloodstream (< 2.3 b.mu g/L) and in key tissues like liver and kidney have not been associated with any disease or disability. Silver is not an acknowledged trace element in the human body and fulfills no physiological or biochemical role in any tissue even though it interacts with several essential elements including zinc and calcium. Physiologically, it exists as an ion in the body. Silver has a long history in the treatment of human diseases, including epilepsy, neonatal eye disease, venereal diseases, and wound infections. It has been employed in water purification and is currently used to safeguard hospital hot water systems against Legionella infections. Principle routes of human exposure to silver nowadays are through its widespread use as an antimicrobial agent in wound care products and medical devices, including in-dwelling catheters, bone cements, cardiac valves and prostheses, orthopedic pins, and dental devices. In each case, the antimicrobial properties of silver are dependent upon release of biologically active silver ion (Ag*) from metallic silver (including nanocrystalline forms), silver nitrate, silver sulfadiazine, and other silver compounds incorporated in the various devices, and its lethal effect on pathogenic organisms.; Experience has shown that a large proportion of the silver ion released from medical devices not required for antimicrobial action is disseminated into tissue fluids and exudates, where it combines with albumins and macroglobulins. These silver-protein complexes are absorbed into the systemic circulation to be deposited in key soft tissues, including the skin, liver, kidney, spleen, lungs, and brain. As a xenobiotic material, silver must be presumed to present a health risk to exposed persons under some circumstances. Unlike the well-documented neurotoxic metals including lead and mercury, silver does not appear to be a cumulative poison and is eliminated from the body through the urine and feces. Excretion of silver by these routes may be a measure of mean daily intake, but since this view is based largely on the clinical use of silver nitrate and silver sulfadiazine used in burn wound therapy, its true relevance in the metabolism of silver used in the wider context of medical devices is questionable.; Argyria is the most widely publicized clinical condition associated with silver accumulation in blood and soft tissues. It commonly occurs in individuals exposed to high levels of silver occupationally (metallurgy, photography, and mining industries), or consuming or inhaling silver hygiene products (including colloidal silver products) for long periods. Silver is absorbed into the body and deposited in the perivascular regions of the skin and other soft tissues as black granules of silver sulfide or silver selenide. The resulting slate grey discoloration of the skin occasionally associated with melanogenic changes, is semipermanent and cosmetically undesirable but is not known to be life-threatening. (PMID: 17453933); The price of silver is important in Judaic Law. The lowest fiscal amount that a Jewish court, or Beth Din, can convene to adjudicate a case over is a shova pruta (value of a Babylonian pruta coin). This is fixed at 1/8 of a gram of pure, unrefined silver, at market price.
CAS Number7440-22-4
Structure
Thumb
Synonyms
SynonymSource
AgChEBI
Ag(0)ChEBI
AgnChEBI
ArgentumChEBI
Silver metalChEBI
Ag+Kegg
AGbiospider
Ag(+)ChEBI
AGNbiospider
Algaedynbiospider
Amalgumbiospider
Argentbiospider
Argent. nit.biospider
Argentum colloidalebiospider
Argentum cyanatumbiospider
Argentum Met.Praep.D8(D10 D12 D15 D20 D30)biospider
Argentum metallicumbiospider
Argentum Metallicum (Silver Metallicum 6x)biospider
Argentum Metallicum 4ch - 30chbiospider
Argentum Mettallicum Gtte 4ch-30chbiospider
Argentum nitricumbiospider
Argentum Nitricum 3ch-30chbiospider
Argentum Nitricum Gtte 5ch-15chbiospider
Argentum nitricum homaccordbiospider
Argentum phosphoricumbiospider
Astroflake 5biospider
Carey lea silverbiospider
Col silbiospider
Colloidal silverbiospider
Collosol argentumbiospider
D 25 (metal)biospider
Degussa 67biospider
Degussa 80biospider
Dermazin Crm 1%biospider
Dotite XA 208biospider
Epinallbiospider
FA 2 (metal)biospider
Flamazine Crm 1%biospider
G 12 (metal)biospider
Germany: C-Pigment 2biospider
Jelcon SH 1biospider
KS (metal)biospider
L-3 (element)biospider
Lead refinery silver bullionbiospider
Liquid silverHMDB
Metz 25Bbiospider
Pekana - argentum metallicumbiospider
Pekana - argentum nitricumbiospider
Platabiospider
Shell silverbiospider
Silberbiospider
Silflake 135biospider
Silpowder 130biospider
SilvadeneHMDB
Silver atombiospider
Silver atomic absorption standard solutionHMDB
Silver atomic spectroscopy standard concentrate 1.00 g Agbiospider
Silver colloidalbiospider
Silver elementalbiospider
Silver granufoambiospider
Silver iodidebiospider
SILVER ionChEBI
Silver ion (1+)ChEBI
Silver ion standard solutionHMDB
Silver Liquid (S#107)-Liqbiospider
Silver metal and soluble compoundsbiospider
Silver nanoparticlesbiospider
Silver Nitrate Liquid (S#106)-Liqbiospider
Silver preparationbiospider
Silver standard for aasbiospider
Silver standard for icpbiospider
Silver, bullionbiospider
Silver, colloidalbiospider
Silver, dispersionbiospider
Silver, elementalbiospider
Silver, Isotope Of Mass 109biospider
Silver, metal and soluble compoundsbiospider
silver(0)biospider
Silver(II)biospider
Ssd (1% silver sulfadiazine cream usp)HMDB
TCG 7rbiospider
Theraworxbiospider
Predicted Properties
PropertyValueSource
logP-0.73ChemAxon
Physiological Charge0ChemAxon
Hydrogen Acceptor Count0ChemAxon
Hydrogen Donor Count0ChemAxon
Polar Surface Area0 ŲChemAxon
Rotatable Bond Count0ChemAxon
Refractivity0 m³·mol⁻¹ChemAxon
Polarizability1.78 ųChemAxon
Number of Rings0ChemAxon
BioavailabilityYesChemAxon
Rule of FiveYesChemAxon
Ghose FilterYesChemAxon
Veber's RuleYesChemAxon
MDDR-like RuleYesChemAxon
Chemical FormulaAg
IUPAC namesilver
InChI IdentifierInChI=1S/Ag
InChI KeyBQCADISMDOOEFD-UHFFFAOYSA-N
Isomeric SMILES[Ag]
Average Molecular Weight107.8682
Monoisotopic Molecular Weight106.90509302
Classification
Description belongs to the class of inorganic compounds known as homogeneous transition metal compounds. These are inorganic compounds containing only metal atoms,with the largest atom being a transition metal atom.
KingdomInorganic compounds
Super ClassHomogeneous metal compounds
ClassHomogeneous transition metal compounds
Sub ClassNot Available
Direct ParentHomogeneous transition metal compounds
Alternative ParentsNot Available
Substituents
  • Homogeneous transition metal
Molecular FrameworkNot Available
External Descriptors
Ontology
OntologyNo ontology term
Physico-Chemical Properties - Experimental
Physico-Chemical Properties - Experimental
PropertyValueReference
Physical stateSolid
Physical DescriptionNot Available
Mass CompositionNot Available
Melting Point960.5 oC
Boiling PointNot Available
Experimental Water SolubilityNot Available
Experimental logPNot Available
Experimental pKaNot Available
Isoelectric pointNot Available
ChargeNot Available
Optical RotationNot Available
Spectroscopic UV DataNot Available
DensityNot Available
Refractive IndexNot Available
Spectra
Spectra
Spectrum TypeDescriptionSplash KeyView
Predicted LC-MS/MSPredicted LC-MS/MS Spectrum - 10V, Positivesplash10-0a4i-0900000000-3126e0d9c9c0db35ef52JSpectraViewer
Predicted LC-MS/MSPredicted LC-MS/MS Spectrum - 20V, Positivesplash10-0a4i-0900000000-3126e0d9c9c0db35ef52JSpectraViewer
Predicted LC-MS/MSPredicted LC-MS/MS Spectrum - 40V, Positivesplash10-0a4i-0900000000-3126e0d9c9c0db35ef52JSpectraViewer
Predicted LC-MS/MSPredicted LC-MS/MS Spectrum - 10V, Negativesplash10-0a4i-0900000000-411976aa2a4fb62a6313JSpectraViewer
Predicted LC-MS/MSPredicted LC-MS/MS Spectrum - 20V, Negativesplash10-0a4i-0900000000-411976aa2a4fb62a6313JSpectraViewer
Predicted LC-MS/MSPredicted LC-MS/MS Spectrum - 40V, Negativesplash10-0a4i-0900000000-411976aa2a4fb62a6313JSpectraViewer
ChemSpider ID94565
ChEMBL IDCHEMBL1230866
KEGG Compound IDC06710
Pubchem Compound ID104755
Pubchem Substance IDNot Available
ChEBI ID9141
Phenol-Explorer IDNot Available
DrugBank IDNot Available
HMDB IDHMDB02659
CRC / DFC (Dictionary of Food Compounds) IDNot Available
EAFUS IDNot Available
Dr. Duke IDSILVER
BIGG IDNot Available
KNApSAcK IDNot Available
HET IDAG
Food Biomarker OntologyNot Available
VMH IDNot Available
Flavornet IDNot Available
GoodScent IDNot Available
SuperScent IDNot Available
Wikipedia IDSilver
Phenol-Explorer Metabolite IDNot Available
Duplicate IDSNot Available
Old DFC IDSNot Available
Associated Foods
FoodContent Range AverageReference
FoodReference
Biological Effects and Interactions
Health Effects / Bioactivities
DescriptorIDDefinitionReference
anti bacterial33282 A substance that kills or slows the growth of bacteria.DUKE
astringent74783 A compound that causes the contraction of body tissues, typically used to reduce bleeding from minor abrasions.DUKE
pesticide25944 Strictly, a substance intended to kill pests. In common usage, any substance used for controlling, preventing, or destroying animal, microbiological or plant pests.DUKE
EnzymesNot Available
PathwaysNot Available
MetabolismNot Available
BiosynthesisNot Available
Organoleptic Properties
FlavoursNot Available
Files
MSDSshow
References
Synthesis ReferenceNot Available
General ReferenceNot Available
Content Reference— Duke, James. 'Dr. Duke's Phytochemical and Ethnobotanical Databases. United States Department of Agriculture.' Agricultural Research Service, Accessed April 27 (2004).